Nitrogen-doped graphene as an efficient metal-free catalyst for ammonia and non-enzymatic glucose sensing

Raza W, Ahmad K, Kim H (2022)


Publication Type: Journal article

Publication year: 2022

Journal

Book Volume: 160

DOI: 10.1016/j.jpcs.2021.110359

Abstract

Theoretical studies reveal that the electronic and chemical properties of graphene can be significantly altered by chemical doping with a nitrogen atom. In the present work, a unique strategy has been applied for the manu-facture of selective N-doped graphene (NG). A low cost, and facile one pot solvothermal approach has been adopted for the synthesis p-type nitrogen graphene. Moreover, the as-synthesized NG sheets exhibit a crossover from n-type to p-type behaviour. The presence of pyridinic-N in graphene planes is confirmed by high-resolution X-ray photoelectron spectroscopy. The as-synthesized NG presents excellent sensing properties towards ammonia, and fast electron transfer kinetics for glucose oxidase. The higher sensing activity is ascribed to synergistic effect of nitrogen, and oxygen-containing functional groups. The resultant NG is proven to act as a metal-free catalyst with much better performance for ammonia and glucose sensing at room temperature. This study will provide a promising potential for the development of NG type sensors in the real world and envi-ronmental applications.

Authors with CRIS profile

Involved external institutions

How to cite

APA:

Raza, W., Ahmad, K., & Kim, H. (2022). Nitrogen-doped graphene as an efficient metal-free catalyst for ammonia and non-enzymatic glucose sensing. Journal of Physics and Chemistry of Solids, 160. https://dx.doi.org/10.1016/j.jpcs.2021.110359

MLA:

Raza, Waseem, Khursheed Ahmad, and Haekyoung Kim. "Nitrogen-doped graphene as an efficient metal-free catalyst for ammonia and non-enzymatic glucose sensing." Journal of Physics and Chemistry of Solids 160 (2022).

BibTeX: Download