Covalent Linkage of BODIPY-Photosensitizers to Anderson-Type Polyoxometalates Using CLICK Chemistry
Cetindere S, Clausing ST, Anjass M, Luo Y, Kupfer S, Dietzek B, Streb C (2021)
Publication Type: Journal article
Publication year: 2021
Journal
Abstract
The covalent attachment of molecular photosensitizers (PS) to polyoxometalates (POMs) opens new pathways to PS-POM dyads for light-driven charge-transfer and charge-storage. Here, we report a synthetic route for the covalent linkage of BODIPY-dyes to Anderson-type polyoxomolybdates by using CLICK chemistry (i. e. copper-catalyzed azide-alkyne cycloaddition, CuAAC). Photophysical properties of the dyad were investigated by combined experimental and theoretical methods and highlight the role of both sub-components for the charge-separation properties. The study demonstrates how CLICK chemistry can be used for the versatile linkage of organic functional units to molecular metal oxide clusters.
Authors with CRIS profile
Involved external institutions
Germany (DE)How to cite
APA:
Cetindere, S., Clausing, S.T., Anjass, M., Luo, Y., Kupfer, S., Dietzek, B., & Streb, C. (2021). Covalent Linkage of BODIPY-Photosensitizers to Anderson-Type Polyoxometalates Using CLICK Chemistry. Chemistry - A European Journal. https://doi.org/10.1002/chem.202102897
MLA:
Cetindere, Seda, et al. "Covalent Linkage of BODIPY-Photosensitizers to Anderson-Type Polyoxometalates Using CLICK Chemistry." Chemistry - A European Journal (2021).
BibTeX: Download