Evaluation of the Efficiency of an Elevated Temperature Proton Exchange Membrane Water Electrolysis System

Bonanno M, Mueller K, Bensmann B, Hanke-Rauschenbach R, Peach R, Thiele S (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Journal of The Electrochemical Society Electrochemical Society

Book Volume: 168

Journal Issue: 9

DOI: 10.1149/1945-7111/ac2188

Abstract

In recent years, a significant interest has been growing in elevated temperature (ET) electrolytes for proton exchange membrane water electrolysis (PEMWE). In this study, the energy and exergy analysis developed for PEMWE has been extended to evaluate the performance of ET-PEMWE, with the model aiming to utilise the energy in the most efficient manner and also take into account potential heat losses. The latter is particularly important considering that heat losses become more pronounced with higher temperature differences. The model shows that the stack operates in autothermic mode over a considerable range of current density. Thus heating inputs to the stack and feed water become progressively unnecessary as polarization losses make up for these heating requirements. This also allows surplus heat to be utilised for secondary applications. The exergy efficiency for ET has been calculated to surpass that for low temperature (LT), with the maximum improvement reaching 3.8% points. Taking into account exergy favours higher temperature differences-a benefit which outweighs the fact that a greater quantity of thermal power is recovered in the LT system (due to higher polarization losses). This finding also shows the suitability of adopting exergy efficiency as the performance indicator for PEMWE systems.

Authors with CRIS profile

Marco Bonanno Professur für Electrocatalytic Interface Engineering (HIERN) Simon Thiele Professur für Electrocatalytic Interface Engineering (HIERN)

Involved external institutions

Gottfried Wilhelm Leibniz Universität Hannover DE Germany (DE) Forschungszentrum Jülich / Research Centre Jülich (FZJ) DE Germany (DE) Universität Rostock DE Germany (DE)

How to cite

APA:

Bonanno, M., Mueller, K., Bensmann, B., Hanke-Rauschenbach, R., Peach, R., & Thiele, S. (2021). Evaluation of the Efficiency of an Elevated Temperature Proton Exchange Membrane Water Electrolysis System. Journal of The Electrochemical Society, 168(9). https://doi.org/10.1149/1945-7111/ac2188

MLA:

Bonanno, Marco, et al. "Evaluation of the Efficiency of an Elevated Temperature Proton Exchange Membrane Water Electrolysis System." Journal of The Electrochemical Society 168.9 (2021).

BibTeX: Download