Hierarchically Dual-Mesoporous TiO2 Microspheres for Enhanced Photocatalytic Properties and Lithium Storage

Xiao S, Lu Y, Li X, Xiao BY, Wu L, Song JP, Xiao YX, Wu SM, Hu J, Wang Y, Chang GG, Tian G, Lenaerts S, Janiak C, Yang XY, Su BL (2018)


Publication Type: Journal article

Publication year: 2018

Journal

Book Volume: 24

Pages Range: 13246-13252

Journal Issue: 50

DOI: 10.1002/chem.201801933

Abstract

Hierarchically dual-mesoporous TiO2 microspheres have been synthesized by a solvothermal process in the presence of 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) and diethylenetriamine (DETA) as co-templates. Secondary mesostructured defects in the hierarchical TiO2 microspheres produce oxygen vacancies, which not only significantly enhance photocatalytic activity in the degradation of methylene blue (1.7 times that with P25) and acetone (2.9 times that with P25), but are also beneficial for lithium storage. Moreover, we propose a mechanism to rationalize the role of this dual mesoporosity of the TiO2 microspheres in enhancing molecular diffusion, ion transportation, and electronic transitions.

Involved external institutions

How to cite

APA:

Xiao, S., Lu, Y., Li, X., Xiao, B.-Y., Wu, L., Song, J.-P.,... Su, B.-L. (2018). Hierarchically Dual-Mesoporous TiO2 Microspheres for Enhanced Photocatalytic Properties and Lithium Storage. Chemistry - A European Journal, 24(50), 13246-13252. https://doi.org/10.1002/chem.201801933

MLA:

Xiao, Sa, et al. "Hierarchically Dual-Mesoporous TiO2 Microspheres for Enhanced Photocatalytic Properties and Lithium Storage." Chemistry - A European Journal 24.50 (2018): 13246-13252.

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