Crystal structures of trans-diiodidobis(2-hydroxyethylamine) platinum(II) and trans-dichloridobis(2,2’-dihydroxydiethylamine) platinum(II)

Heinemann FW, Bugarčić ŽD, Soldatović TV (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Journal Macroheterocycles Ivanovo State University of Chemistry and Technology

Book Volume: 13

Pages Range: 210-214

Journal Issue: 3

DOI: 10.6060/mhc200389s

Abstract

The crystal structures of trans-diiodidobis(2-hydroxyethylamine)platinum(II), trans-[PtI2 (mea)2 ], (1) and transdichloridobis(2,2’-dihydroxydiethylamine)platinum(II), trans-[PtCl2 (dea)2 ], (2) were determined by single crystal X-ray diffraction experiments. Crystallization of (1) occurs in the monoclinic space group P21 /c with a = 9.457(1) Å, b = 14.719(2) Å, c = 8.246(1) Å, Z = 4 for dcalc = 3.235 mg/m3 while crystallization of (2) occurs in the tetragonal space group P42 /mbc, a = 9.8624(6) Å, c = 14.2998(9) Å, Z = 4 for dcalc = 2.274 mg/m3. The square-planar coordination geometry of both complexes is formed by two N atoms of the 2-hydroxyethylamine (1) or 2,2’-dihydroxydiethylamine (2) ligands in trans positions and two I- (1) or Cl- (2) anions. Both structures are stabilized by intra-and intermolecular hydrogen bonds.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

State University of Novi Pazar RS Serbia (RS) University of Kragujevac RS Serbia (RS)

How to cite

APA:

Heinemann, F.W., Bugarčić, Ž.D., & Soldatović, T.V. (2020). Crystal structures of trans-diiodidobis(2-hydroxyethylamine) platinum(II) and trans-dichloridobis(2,2’-dihydroxydiethylamine) platinum(II). Journal Macroheterocycles, 13(3), 210-214. https://doi.org/10.6060/mhc200389s

MLA:

Heinemann, Frank Wilhelm, Živadin D. Bugarčić, and Tanja V. Soldatović. "Crystal structures of trans-diiodidobis(2-hydroxyethylamine) platinum(II) and trans-dichloridobis(2,2’-dihydroxydiethylamine) platinum(II)." Journal Macroheterocycles 13.3 (2020): 210-214.

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