Martin M, Oleszak C, Hampel F, Jux N (2020)
Publication Type: Journal article
Publication year: 2020
Book Volume: 2020
Pages Range: 6758-6762
Journal Issue: 43
The extension of the aromatic π-system of porphyrins is a powerful method to alter their optoelectronic properties. Herein, aryl substituents were fused to porphyrin cores by Scholl oxidation reactions that selectively produced mono- and doubly-fused porphyrins in yields of up to 69 %. Several different aryl substituents attached to the porphyrin were investigated with respect to their reactivity under Scholl conditions. The fused products were fully characterized, i.e., by UV/Vis absorption spectroscopy, which showed drastic changes in the electronic features. Insight into the solid-state behavior was obtained by X-ray crystallography. Our approach represents a novel option for the late-stage functionalization of porphyrin-based compounds.
APA:
Martin, M., Oleszak, C., Hampel, F., & Jux, N. (2020). Oxidative Cyclodehydrogenation Reactions with Tetraarylporphyrins. European Journal of Organic Chemistry, 2020(43), 6758-6762. https://doi.org/10.1002/ejoc.202001174
MLA:
Martin, Max, et al. "Oxidative Cyclodehydrogenation Reactions with Tetraarylporphyrins." European Journal of Organic Chemistry 2020.43 (2020): 6758-6762.
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