Rösch B, Gentner T, Eyselein J, Friedrich A, Langer J, Harder S (2020)
Publication Type: Journal article
Publication year: 2020
Book Volume: 56
Pages Range: 11402-11405
Journal Issue: 77
DOI: 10.1039/d0cc05200k
The bulk of a recently reported superbulky β-diketiminate ligand was further increased by introducing tBu substituents in the ligand backbone. Attempts to isolate free Mg radicals with this extremely bulky ligand failed. Instead, a dinuclear Mg(i) complex with one chelating and one monodentate β-diketiminate ligand was isolated. Asymmetry in metal coordination results in a polarized Mg-Mg bond.
APA:
Rösch, B., Gentner, T., Eyselein, J., Friedrich, A., Langer, J., & Harder, S. (2020). Mg-Mg bond polarization induced by a superbulky β-diketiminate ligand. Chemical Communications, 56(77), 11402-11405. https://doi.org/10.1039/d0cc05200k
MLA:
Rösch, Bastian, et al. "Mg-Mg bond polarization induced by a superbulky β-diketiminate ligand." Chemical Communications 56.77 (2020): 11402-11405.
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