Stefanopoulos KL, Katsaros FK, Steriotis TA, Sapalidis AA, Thommes M, Bowron DT, Youngs TGA (2016)
Publication Type: Journal article, Original article
Subtype: other
Publication year: 2016
Book Volume: 116
Pages Range: 025502
Journal Issue: 2
DOI: 10.1103/PhysRevLett.116.025502
The phase behavior of sorbed CO{2} in an ordered mesoporous silica sample (SBA-15) was studied by neutron diffraction. Surprisingly, upon cooling our sample below the bulk critical point, confined CO{2} molecules neither freeze nor remain liquid as expected, but escape from the pores. The phenomenon has additionally been confirmed gravimetrically. The process is reversible and during heating CO{2} refills the pores, albeit with hysteresis. This depletion was for the first time observed in an ordered mesoporous molecular sieve and provides new insight on the phase behavior of nanoconfined fluids.[on SciFinder (R)]
APA:
Stefanopoulos, K.L., Katsaros, F.K., Steriotis, T.A., Sapalidis, A.A., Thommes, M., Bowron, D.T., & Youngs, T.G.A. (2016). Anomalous Depletion of Pore-Confined Carbon Dioxide upon Cooling below the Bulk Triple Point: An In Situ Neutron Diffraction Study. Physical Review Letters, 116(2), 025502. https://doi.org/10.1103/PhysRevLett.116.025502
MLA:
Stefanopoulos, K. L., et al. "Anomalous Depletion of Pore-Confined Carbon Dioxide upon Cooling below the Bulk Triple Point: An In Situ Neutron Diffraction Study." Physical Review Letters 116.2 (2016): 025502.
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