Moegling J, Hoffmann A, Thomas F, Orth N, Liebhaeuser P, Herber U, Rampmaier R, Stanek J, Fink G, Ivanovic-Burmazovic I, Herres-Pawlis S (2018)
Publication Status: Published
Publication Type: Journal article
Publication year: 2018
tBuPhINTs and copper(I) acetonitrile complexes. Their stoichiometric reactivity has been elucidated regarding the imination of phosphines and the aziridination of styrenes. The formation and thermal decay of the copper nitrenes were investigated by UV/Vis spectroscopy of the highly coloured species. Additionally, the compounds were studied by cryo-UHR-ESI mass spectrometry and DFT calculations. In addition, a mild catalytic procedure has been developed where the copper nitrene precursors enable the C-H amination of cyclohexane and toluene and the aziridination of styrenes.
APA:
Moegling, J., Hoffmann, A., Thomas, F., Orth, N., Liebhaeuser, P., Herber, U.,... Herres-Pawlis, S. (2018). Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C-H Aminations. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201713171
MLA:
Moegling, Julian, et al. "Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C-H Aminations." Angewandte Chemie International Edition (2018).
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