Eger WA, Grange RL, Schill H, Goumont R, Clark T, Williams CM (2011)
Publication Status: Published
Publication Type: Journal article
Publication year: 2011
Publisher: Wiley-VCH Verlag
Pages Range: 2548-2553
Journal Issue: 13
Acyl anion equivalents (umpolung) are the practitioner's first choice en route to 1,3-hydroxy keto compounds from epoxides. Why? This investigation evaluates computationally and experimentally the reactivity of a near comprehensive range of acyl anion equivalents using epoxide ring opening as a test vehicle. Reactivity understanding, reactivity order, surprise failures in performance, along with unprecedented, but far from superior, reactivity of TosMIC is presented for the first time.
APA:
Eger, W.A., Grange, R.L., Schill, H., Goumont, R., Clark, T., & Williams, C.M. (2011). Understanding the Reactivity of Acyl Anion Equivalents: The Epoxide Ring Opening Case. European Journal of Organic Chemistry, 13, 2548-2553. https://doi.org/10.1002/ejoc.201001680
MLA:
Eger, Wilhelm A., et al. "Understanding the Reactivity of Acyl Anion Equivalents: The Epoxide Ring Opening Case." European Journal of Organic Chemistry 13 (2011): 2548-2553.
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