Lauter M, Breitinger D, Breiter R, Mink J, Bencze E (2001)
Publication Language: English
Publication Status: Published
Publication Type: Journal article, Original article
Publication year: 2001
Publisher: Elsevier
Book Volume: 563
Pages Range: 383-388
DOI: 10.1016/S0022-2860(00)00795-X
Ambient- and low-temperature IR. FIR and FT-Raman spectra of the complexes trans-[RuX(NH/D-3)(4)SO2]X (X = Cl (1/1D), Br (2/2D), I(3/3D)) were measured to provide the bases for normal coordinate analyses (NCA). Further, X-ray structure analyses of 1-3 yielded the required bonding parameters and justify the assumption of an idealized symmetry C-2v-mm2 for the cations. In accordance with the results of the structure determinations, the NCA calculations show an increasing irans-influence of the halogeno ligand on the Ru-S bond in the series Cl < Br < I. Formerly estimated force constants f(r)(RuN) are confirmed and neglect of cis-interactions is justified. Inspections of the eigenvalues and the potential energy distributions show an intense mixing of valence and deformation vibrations in symmetry species A(1). (C) 2001 Elsevier Science B.V. All rights reserved.
APA:
Lauter, M., Breitinger, D., Breiter, R., Mink, J., & Bencze, E. (2001). Normal coordinate analyses of ruthenium-sulfur dioxide complexes. Journal of Molecular Structure, 563, 383-388. https://doi.org/10.1016/S0022-2860(00)00795-X
MLA:
Lauter, M, et al. "Normal coordinate analyses of ruthenium-sulfur dioxide complexes." Journal of Molecular Structure 563 (2001): 383-388.
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