Göller AH, Clark T (1997)
Publication Status: Published
Publication Type: Journal article
Publication year: 1997
Publisher: Royal Society of Chemistry
Pages Range: 1033-1034
Journal Issue: 11
DOI: 10.1039/a701788j
Ab initio (CCSD(T)/6-31+G*) calculations suggest that 1H-phosphiranes and 1H-phosphirenes invert their configuration at phosphorus by a rotation of the PX group (X = H, F, Cl, Br) above the C-2 moiety, rather than the more usual planar trigonal inversion pathway via a C-2v transition state.
APA:
Göller, A.H., & Clark, T. (1997). 1H-phosphiranes and -enes invert at phosphorus via a turnstile rotation. Chemical Communications, 11, 1033-1034. https://doi.org/10.1039/a701788j
MLA:
Göller, Andreas H., and Timothy Clark. "1H-phosphiranes and -enes invert at phosphorus via a turnstile rotation." Chemical Communications 11 (1997): 1033-1034.
BibTeX: Download