Home Publications Research Grants Inventions & Patents Awards Additional Research Activities Faculties & Institutions Research Areas

A planar three-coordinate vanadium(II) complex and the study of terminal vanadium nitrides from N 2: A kinetic or thermodynamic impediment to N-N bond cleavage?

Tran BL, Pinter B, Nichols AJ, Konopka FT, Thompson R, Chen CH, Krzystek J, Ozarowski A, Telser J, Baik MH, Meyer K, Mindiola DJ (2012)

---

Publication Type: Journal article, Original article

Publication year: 2012

Journal

Original Authors: Tran B.L., Pinter B., Nichols A.J., Konopka F.T., Thompson R., Chen C.-H., Krzystek J., Ozarowski A., Telser J., Baik M.-H., Meyer K., Mindiola D.J.

Publisher: American Chemical Society

Book Volume: 134

Pages Range: 13035-13045

Journal Issue: 31

DOI: 10.1021/ja303360v

Abstract

We report the first mononuclear three-coordinate vanadium(II) complex [(nacnac)V(ODiiP)] and its activation of N to form an end-on bridging dinitrogen complex with a topologically linear V(III)N V(III) core and where each vanadium center antiferromagnetically couples to give a ground state singlet with an accessible triplet state as inferred by HFEPR spectroscopy. In addition to investigating the conversion of N to the terminal nitride (as well as the microscopic reverse process), we discuss its similarities and contrasts to the isovalent d system, [Mo(N[ Bu]Ar) ], and the S = 1 system [(Ar[ Bu]N) Mo] (μ - η :η -N ). © 2012 American Chemical Society.

Authors with CRIS profile

Involved external institutions

How to cite

APA:

Tran, B.L., Pinter, B., Nichols, A.J., Konopka, F.T., Thompson, R., Chen, C.-H.,... Mindiola, D.J. (2012). A planar three-coordinate vanadium(II) complex and the study of terminal vanadium nitrides from N 2: A kinetic or thermodynamic impediment to N-N bond cleavage? Journal of the American Chemical Society, 134(31), 13035-13045. https://doi.org/10.1021/ja303360v

MLA:

Tran, Ba L., et al. "A planar three-coordinate vanadium(II) complex and the study of terminal vanadium nitrides from N 2: A kinetic or thermodynamic impediment to N-N bond cleavage?" Journal of the American Chemical Society 134.31 (2012): 13035-13045.

BibTeX: Download