Synthesis of polyyne rotaxanes

Movsisyan LD, Kondratuk DV, Franz M, Thompson AL, Tykwinski R, Anderson HL (2012)

Publication Type: Journal article, Original article

Publication year: 2012

Journal

Organic Letters American Chemical Society

Original Authors: Movsisyan L.D., Kondratuk D.V., Franz M., Thompson A.L., Tykwinski R.R., Anderson H.L.

Publisher: American Chemical Society

Book Volume: 14

Pages Range: 3424-3426

Journal Issue: 13

DOI: 10.1021/ol301392t

Abstract

Active-metal templating has been used to synthesize rotaxanes consisting of a phenanthroline-based macrocycle threaded around a C8, C12, or C20 polyyne chain. The crystal structure of the C12 rotaxane has been determined. In the rhenium(I) carbonyl complex of this rotaxane, with Re(CO) Cl coordinated to the phenanthroline macrocycle, the proximity of the polyyne chain quenches the luminescence of the rhenium. These rotaxanes offer a new approach to controlling the environment and interactions of a polyyne chain. © 2012 American Chemical Society.

Authors with CRIS profile

Michael Franz Lehrstuhl für Organische Chemie I Rik Tykwinski Lehrstuhl für Organische Chemie I

Involved external institutions

University of Oxford GB United Kingdom (GB)

How to cite

APA:

Movsisyan, L.D., Kondratuk, D.V., Franz, M., Thompson, A.L., Tykwinski, R., & Anderson, H.L. (2012). Synthesis of polyyne rotaxanes. Organic Letters, 14(13), 3424-3426. https://doi.org/10.1021/ol301392t

MLA:

Movsisyan, Levon D., et al. "Synthesis of polyyne rotaxanes." Organic Letters 14.13 (2012): 3424-3426.

BibTeX: Download