Covalent and noncovalent phthalocyanine - Carbon nanostructure systems: Synthesis, photoinduced electron transfer, and application to molecular photovoltaics
Bottari G, De La Torre G, Guldi DM, Torres T (2010)
Publication Type: Journal article, Original article
Publication year: 2010
Journal
Original Authors: Bottari G., De La Torre G., Guldi D.M., Torres T.
Publisher: American Chemical Society
Book Volume: 110
Pages Range: 6768-6816
Journal Issue: 11
DOI: 10.1021/cr900254z
Abstract
The tunable absorption features of phthalocyanine (Pcs) and related compounds such as subphthalocyanines (SubPcs) render them ideal antenna systems that harvest light over a broad range of the solar spectrum. The different synthetic strategies that have been pursued so far for the preparation of D-A Pc and SubPc-carbon nanostructure systems, having the donor and the acceptor units connected either covalently or by using supramolecular interactions were studied. A thorough analysis on the photophysical properties of dyads in solution was also carried out, confirming the occurrence of PET events. Transmission electron microscopy (TEM) studies revealed that the amphiphilic Pc-C60 dyad salt, when dispersed in water, is able to form perfectly ordered 1-D nanotubules, due to a combination of solvophobic and π-π stacking interactions. One of the most outstanding applications of these materials is their incorporation in photovoltaic devices in which generation of electrical current from solar energy takes place.
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APA:
Bottari, G., De La Torre, G., Guldi, D.M., & Torres, T. (2010). Covalent and noncovalent phthalocyanine - Carbon nanostructure systems: Synthesis, photoinduced electron transfer, and application to molecular photovoltaics. Chemical Reviews, 110(11), 6768-6816. https://doi.org/10.1021/cr900254z
MLA:
Bottari, Giovanni, et al. "Covalent and noncovalent phthalocyanine - Carbon nanostructure systems: Synthesis, photoinduced electron transfer, and application to molecular photovoltaics." Chemical Reviews 110.11 (2010): 6768-6816.
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