Yao S, Szilvasi T, Lindenmaier N, Xiong Y, Inoue S, Adelhardt M, Sutter J, Meyer K, Driess M (2015)
Publication Status: Published
Publication Type: Journal article
Publication year: 2015
Publisher: Royal Society of Chemistry
Book Volume: 51
Pages Range: 6153-6156
DOI: 10.1039/c5cc00147a
The selective transformation of white phosphorus with a beta-diketiminato iron(I) toluene complex under mild reaction conditions is reported which furnishes a new dinuclear iron(III) Fe-2(P-2)(2) complex with two bridging P-2(2-) ligands. Its reduction with potassium results in the formation of the first delocalised mixed-valent bis-diphosphido iron(II,III) complex which is isostructural with the neutral Fe2P4 precursor.
APA:
Yao, S., Szilvasi, T., Lindenmaier, N., Xiong, Y., Inoue, S., Adelhardt, M.,... Driess, M. (2015). Reductive cleavage of P-4 by iron(I) centres: synthesis and structural characterisation of Fe-2(P-2)(2) complexes with two bridging P-2(2-) ligands. Chemical Communications, 51, 6153-6156. https://doi.org/10.1039/c5cc00147a
MLA:
Yao, Shenglai, et al. "Reductive cleavage of P-4 by iron(I) centres: synthesis and structural characterisation of Fe-2(P-2)(2) complexes with two bridging P-2(2-) ligands." Chemical Communications 51 (2015): 6153-6156.
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