Kinetics of the CO oxidation reaction on Pt(111) studied by in situ high-resolution x-ray photoelectron spectroscopy

Kinne M, Fuhrmann T, Zhu J, Whelan C, Denecke R, Steinrück HP (2004)


Publication Type: Journal article

Publication year: 2004

Journal

Original Authors: Kinne M., Fuhrmann T., Zhu J.F., Whelan C.M., Denecke R., Steinrück H.-P.

Publisher: American Institute of Physics (AIP)

Book Volume: 120

Pages Range: 7113-7122

Journal Issue: 15

DOI: 10.1063/1.1669378

Abstract

The coadsorption and reaction of CO with atomic oxygen on Pt(111) was examined by in situ high-resolution core level spectroscopy using synchrotron radiation. A atomic oxygen layer with a coverage of 0.25 ML was exposed to CO from a supersonic molecular beam at various sample temperatures and pressures. X ray photoelectron spectra were collected at photon energies of 380 eV for C 1s and 650 eV for the O 1s region in normal emission geometry. From an Arrhenius plot of the rate constant between 275 and 305 K an activation energy of (0.53±0.04) eV and a prefactor of 4.7×10 s were determined.

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How to cite

APA:

Kinne, M., Fuhrmann, T., Zhu, J., Whelan, C., Denecke, R., & Steinrück, H.-P. (2004). Kinetics of the CO oxidation reaction on Pt(111) studied by in situ high-resolution x-ray photoelectron spectroscopy. Journal of Chemical Physics, 120(15), 7113-7122. https://doi.org/10.1063/1.1669378

MLA:

Kinne, Martin, et al. "Kinetics of the CO oxidation reaction on Pt(111) studied by in situ high-resolution x-ray photoelectron spectroscopy." Journal of Chemical Physics 120.15 (2004): 7113-7122.

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