Reactivity studies of a masked three-coordinate vanadium(II) complex

Tran BL, Singhal M, Park H, Lam OP, Pink M, Krzystek J, Ozarowski A, Telser J, Meyer K, Mindiola DJ (2010)

Publication Type: Journal article, Original article

Publication year: 2010

Journal

Angewandte Chemie International Edition Wiley

Original Authors: Tran B.L., Singhal M., Park H., Lam O.P., Pink M., Krzystek J., Ozarowski A., Telser J., Meyer K., Mindiola D.J.

Publisher: Wiley-VCH Verlag

Book Volume: 49

Pages Range: 9871-9875

Journal Issue: 51

DOI: 10.1002/anie.201005029

Abstract

An arene interaction can mask a low-valent and low-coordinate V complex, [(nacnac)V(Ntol)] (see structure), which allows for facile coordination of terminal ligands on the vanadium center. Small-molecule activation by this S=3/2 complex provides facile access to a wide range of ligand frameworks such as terminal V imido, V cyclopropene, V nitride, and the first V cyclo-P complex (see scheme). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Authors with CRIS profile

Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Indiana University US United States (USA) (US) Florida State University (FSU) US United States (USA) (US) Roosevelt University US United States (USA) (US)

How to cite

APA:

Tran, B.L., Singhal, M., Park, H., Lam, O.P., Pink, M., Krzystek, J.,... Mindiola, D.J. (2010). Reactivity studies of a masked three-coordinate vanadium(II) complex. Angewandte Chemie International Edition, 49(51), 9871-9875. https://doi.org/10.1002/anie.201005029

MLA:

Tran, Ba L., et al. "Reactivity studies of a masked three-coordinate vanadium(II) complex." Angewandte Chemie International Edition 49.51 (2010): 9871-9875.

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