Insights into the mechanism of carbonate formation through reductive cleavage of carbon dioxide with low-valent uranium centers

Lam OP, Bart SC, Kameo H, Heinemann FW, Meyer K (2010)

Publication Type: Journal article, Original article

Publication year: 2010

Journal

Chemical Communications Royal Society of Chemistry

Original Authors: Lam O.P., Bart S.C., Kameo H., Heinemann F.W., Meyer K.

Publisher: Royal Society of Chemistry

Book Volume: 46

Pages Range: 3137-3139

Journal Issue: 18

DOI: 10.1039/b927142b

Abstract

The low-valent U(iii) complexes [(( ArO) mes)U] and [(( ArO) N)U] react with CO to form the bridging carbonate complexes [{(( ArO) mes)U} (μ-κ :κ -CO )] and [{(( ArO) N)U} (μ-η : κ -CO )]. Uranium(iv) bridging oxo complexes have been determined to be the intermediate in these transformations. © The Royal Society of Chemistry 2010.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

How to cite

APA:

Lam, O.P., Bart, S.C., Kameo, H., Heinemann, F.W., & Meyer, K. (2010). Insights into the mechanism of carbonate formation through reductive cleavage of carbon dioxide with low-valent uranium centers. Chemical Communications, 46(18), 3137-3139. https://doi.org/10.1039/b927142b

MLA:

Lam, Oanh P., et al. "Insights into the mechanism of carbonate formation through reductive cleavage of carbon dioxide with low-valent uranium centers." Chemical Communications 46.18 (2010): 3137-3139.

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