C-C Bond Formation through Reductive Coupling of CS 2 to Yield Uranium Tetrathiooxalate and Ethylenetetrathiolate Complexes

Lam OP, Heinemann FW, Meyer K (2011)

Publication Type: Journal article, Original article

Publication year: 2011

Journal

Angewandte Chemie International Edition Wiley

Original Authors: Lam O.P., Heinemann F.W., Meyer K.

Publisher: Wiley-VCH Verlag

Book Volume: 50

Pages Range: 5965-5968

Journal Issue: 26

DOI: 10.1002/anie.201101185

Abstract

A novel twist: The U complex [(( ArO) N)U] reacts with CS by reductive coupling to form the tetrathiooxalate complex [{(( ArO) N)U} (- : -C S )] with a newly formed C-C bond (see scheme). The U /U tetrathiooxalate complex features a nonplanar C S unit in an unprecedented - : binding mode. Further reduction gives the ethylenetetrathiolate complex [Na(dme) ] [{(( ArO) N)U} (-C S )]. DME=1,2-dimethoxyethane. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

How to cite

APA:

Lam, O.P., Heinemann, F.W., & Meyer, K. (2011). C-C Bond Formation through Reductive Coupling of CS 2 to Yield Uranium Tetrathiooxalate and Ethylenetetrathiolate Complexes. Angewandte Chemie International Edition, 50(26), 5965-5968. https://doi.org/10.1002/anie.201101185

MLA:

Lam, Oanh P., Frank Wilhelm Heinemann, and Karsten Meyer. "C-C Bond Formation through Reductive Coupling of CS 2 to Yield Uranium Tetrathiooxalate and Ethylenetetrathiolate Complexes." Angewandte Chemie International Edition 50.26 (2011): 5965-5968.

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