Wiese S, Badiei YM, Gephart RT, Mossin S, Varonka MS, Melzer MM, Meyer K, Cundari TR, Warren TH (2010)
Publication Type: Journal article, Original article
Publication year: 2010
Original Authors: Wiese S., Badiei Y.M., Gephart R.T., Mossin S., Varonka M.S., Melzer M.M., Meyer K., Cundari T.R., Warren T.H.
Publisher: Wiley-VCH Verlag
Book Volume: 49
Pages Range: 8850-8855
Journal Issue: 47
En route to catalysis: Two equivalents of the three-coordinate copper(II) amide [(Cl NN)Cu]-NHAd participate in stoichiometric C - H amination by a H-atom abstraction/radical capture sequence. This active species may be generated through a copper(II) tert-butoxide intermediate to allow for the unprecedented catalytic amination of sp -C - H bonds with unactivated alkylamines. This method greatly expands the range of amines for catalytic C - H amination since most protocols require N-based electron-withdrawing groups. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
APA:
Wiese, S., Badiei, Y.M., Gephart, R.T., Mossin, S., Varonka, M.S., Melzer, M.M.,... Warren, T.H. (2010). Catalytic C - H amination with unactivated amines through copper(II) amides. Angewandte Chemie International Edition, 49(47), 8850-8855. https://doi.org/10.1002/anie.201003676
MLA:
Wiese, Stefan, et al. "Catalytic C - H amination with unactivated amines through copper(II) amides." Angewandte Chemie International Edition 49.47 (2010): 8850-8855.
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