A square-planar ruthenium(II) complex with a low-spin configuration
Askevold B, Khusniyarov M, Herdtweck E, Meyer K, Schneider S (2010)
Publication Type: Journal article, Original article
Publication year: 2010
Journal
Original Authors: Askevold B., Khusniyarov M.M., Herdtweck E., Meyer K., Schneider S.
Publisher: Wiley-VCH Verlag
Book Volume: 49
Pages Range: 7566-7569
Journal Issue: 41
Abstract
Ground-about: The ruthenium(II) complex [RuCl{N(CH CH PtBu ) }] (B) is obtained in high yield by the reaction of [RuCl {HN(CH CH PtBu ) }] (A) with KOtBu. Complex B exhibits an unusual electronic low-spin (S=0) ground-state configuration. Comparison with Caulton's [RuCl{N(SiMe CH PtBu ) }] (ground state: S=1) shows that the ground-state spin multiplicity in these complexes is controlled by the N→Ru π-donor strength. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
Authors with CRIS profile
Marat Khusniyarov
Lehrstuhl für Anorganische und Allgemeine Chemie
Karsten Meyer
Lehrstuhl für Anorganische und Allgemeine Chemie
Involved external institutions
Germany (DE)How to cite
APA:
Askevold, B., Khusniyarov, M., Herdtweck, E., Meyer, K., & Schneider, S. (2010). A square-planar ruthenium(II) complex with a low-spin configuration. Angewandte Chemie International Edition, 49(41), 7566-7569. https://doi.org/10.1002/anie.201002296
MLA:
Askevold, Bjorn, et al. "A square-planar ruthenium(II) complex with a low-spin configuration." Angewandte Chemie International Edition 49.41 (2010): 7566-7569.
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