Eberhard J, Peuntinger K, Rath S, Neumann B, Stammler HG, Guldi DM, Mattay J (2014)
Publication Type: Journal article, Original article
Publication year: 2014
Original Authors: Eberhard J., Peuntinger K., Rath S., Neumann B., Stammler H.-G., Guldi D.M., Mattay J.
Publisher: Royal Society of Chemistry
Book Volume: 13
Pages Range: 380-396
Journal Issue: 2
DOI: 10.1039/c3pp50349f
The homoleptic zinc(ii) and ruthenium(ii) metal complexes of bis(tridentate) 9-acridine and 10-methyl-9-acridinium-substituted terpyridines were tested for their suitability as triplet photosensitizers (PS) using the photooxidation of 1,5-dihydroxynaphthalene (DHN) to Juglone as a model reaction. Singlet oxygen (OΔ) generation is superior or comparable to Ru(bpy) for the acridine complexes, whereas the acridinium complexes are ineffective. The molecular structure of the bis(9-(5-([2,2′:6′,2′′-terpyridin]- 4′-yl)thien-2-yl)-10-methylacridinium)zinc(ii) complex ([Zn(MeATT) ][PF]) is determined by X-ray structure analysis, whereas for other complexes DFT calculations were performed for structural parameters to obtain insights into their electronic properties. This journal is © The Royal Society of Chemistry and Owner Societies.
APA:
Eberhard, J., Peuntinger, K., Rath, S., Neumann, B., Stammler, H.-G., Guldi, D.M., & Mattay, J. (2014). A study of acridine and acridinium-substituted bis(terpyridine)zinc(ii) and ruthenium(ii) complexes as photosensitizers for O2 ( 1Δg) generation. Photochemical & Photobiological Sciences, 13(2), 380-396. https://doi.org/10.1039/c3pp50349f
MLA:
Eberhard, Jens, et al. "A study of acridine and acridinium-substituted bis(terpyridine)zinc(ii) and ruthenium(ii) complexes as photosensitizers for O2 ( 1Δg) generation." Photochemical & Photobiological Sciences 13.2 (2014): 380-396.
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