Cyclopentadienylruthenium π complexes of subphthalocyanines: A "drop-pin" approach to modifying the electronic features of aromatic macrocycles

Caballero E, Fernandez-Ariza J, Lynch VM, Nieto CR, Salome Rodriguez-Morgade M, Sessler JL, Guldi DM, Torres T (2012)


Publication Type: Journal article, Original article

Publication year: 2012

Journal

Original Authors: Caballero E., Fernandez-Ariza J., Lynch V.M., Romero-Nieto C., Rodriguez-Morgade M.S., Sessler J.L., Guldi D.M., Torres T.

Publisher: Wiley-VCH Verlag

Book Volume: 51

Pages Range: 11337-11342

Journal Issue: 45

DOI: 10.1002/anie.201206111

Abstract

Facing facts: Coordination of Cp*Ru (Cp*=CMe ) to the concave and convex π surfaces of subphthalocyanines constitutes a new approach to the functionalization of subazaporphyrins. While the convex face shows higher reactivity, coordination to the concave side produces a stronger diatropic influence on the Cp* ligand and a greater perturbation of the macrocyclic π-electronic features. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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APA:

Caballero, E., Fernandez-Ariza, J., Lynch, V.M., Nieto, C.R., Salome Rodriguez-Morgade, M., Sessler, J.L.,... Torres, T. (2012). Cyclopentadienylruthenium π complexes of subphthalocyanines: A "drop-pin" approach to modifying the electronic features of aromatic macrocycles. Angewandte Chemie International Edition, 51(45), 11337-11342. https://doi.org/10.1002/anie.201206111

MLA:

Caballero, Esmeralda, et al. "Cyclopentadienylruthenium π complexes of subphthalocyanines: A "drop-pin" approach to modifying the electronic features of aromatic macrocycles." Angewandte Chemie International Edition 51.45 (2012): 11337-11342.

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