Organosulfur-based fullerene materials

Nakahodo T, Ishitsuka MO, Takano Y, Tsuchiya T, Akasaka T, Herranz MA, Martin N, Guldi DM, Nagase S (2011)

Publication Type: Journal article, Original article

Publication year: 2011

Journal

Phosphorus Sulfur and Silicon and the Related Elements Taylor & Francis: STM, Behavioural Science and Public Health Titles / Taylor & Francis

Original Authors: Nakahodo T., Ishitsuka M.O., Takano Y., Tsuchiya T., Akasaka T., Angeles Herranz M., Martin N., Guldi D.M., Nagase S.

Publisher: Taylor & Francis: STM, Behavioural Science and Public Health Titles / Taylor & Francis

Book Volume: 186

Pages Range: 1308-1311

Journal Issue: 5

DOI: 10.1080/10426507.2010.523033

Abstract

Chemical functionalizations of an endohedral metallofullerene, La @I-C, and an empty fullerene, C , are demonstrated using organosulfur compounds. A novel donor-acceptor system of La@I-C-exTTF (3) synthesized using the Prato reaction shows photo-induced intramolecular charge separation. On the other hand, the photoreaction of C with N-ptoluenesulfonyl sulfilimine affords N-tosyl-1,2-aziridinofullerene (5). The first reversible interconversion of 1,2-aziridinofullerene and 1,6-azafulleroid was found for mono-substituted fullerenes by thermal rearrangement of 5 to 6. S,S-Diphenylsulfilimines (7) with an electrondonating group on the N atom reacts with C to afford corresponding aziridinofullerenes (8-10) regioselectively. Copyright © Taylor & Francis Group, LLC.

Authors with CRIS profile

Dirk Michael Guldi Lehrstuhl für Physikalische Chemie I

Involved external institutions

National Institute of Natural Sciences (NINS) / 自然科学研究機構 JP Japan (JP) Universidad Complutense de Madrid (UCM) ES Spain (ES) University of Tsukuba / 筑波大学 JP Japan (JP)

How to cite

APA:

Nakahodo, T., Ishitsuka, M.O., Takano, Y., Tsuchiya, T., Akasaka, T., Herranz, M.A.,... Nagase, S. (2011). Organosulfur-based fullerene materials. Phosphorus Sulfur and Silicon and the Related Elements, 186(5), 1308-1311. https://doi.org/10.1080/10426507.2010.523033

MLA:

Nakahodo, Tsukasa, et al. "Organosulfur-based fullerene materials." Phosphorus Sulfur and Silicon and the Related Elements 186.5 (2011): 1308-1311.

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