Assembling phthalocyanine dimers through a platinum(II) acetylide linker
Jimenez AJ, Luisa Marcos M, Hausmann A, Salome Rodriguez-Morgade M, Guldi DM, Torres T (2011)
Publication Type: Journal article, Original article
Publication year: 2011
Journal
Original Authors: Jimenez A.J., Marcos M.L., Hausmann A., Rodriguez-Morgade M.S., Guldi D.M., Torres T.
Publisher: Wiley-VCH Verlag
Book Volume: 17
Pages Range: 14139-14146
Journal Issue: 50
Abstract
Phthalocyanine (Pc) dimers connected through trans-platinum(II) diacetylide linkers have been prepared by reaction of the corresponding ethynylphthalocyanines with trans-bis(triethylphosphine)platinum(II) chloride. Special emphasis was placed on the analysis of the ground- and excited-state features of these compounds in relation to butadiyne-bridged Pc dimers and the corresponding monomers. Both Zn -containing Pc dimers exhibit long-lived triplet excited states. The insertion of σ-bonded trans-platinum(II) diacetylide spacers decoupled the two Pc groups and led to an appreciable acceleration (by a factor of up to 10) of the radiative and nonradiative decay rate of the singlet and triplet excited states. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Authors with CRIS profile
Anita Hausmann
Lehrstuhl für Physikalische Chemie I
Dirk Michael Guldi
Lehrstuhl für Physikalische Chemie I
Involved external institutions
Spain (ES)How to cite
APA:
Jimenez, A.J., Luisa Marcos, M., Hausmann, A., Salome Rodriguez-Morgade, M., Guldi, D.M., & Torres, T. (2011). Assembling phthalocyanine dimers through a platinum(II) acetylide linker. Chemistry - A European Journal, 17(50), 14139-14146. https://doi.org/10.1002/chem.201101791
MLA:
Jimenez, Angel J., et al. "Assembling phthalocyanine dimers through a platinum(II) acetylide linker." Chemistry - A European Journal 17.50 (2011): 14139-14146.
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