A new exTTF-crown ether platform to associate fullerenes: Cooperative n-π and π-π Effects

Grimm B, Santos J, Illescas BM, Munoz A, Guldi DM, Martin N (2010)

Publication Type: Journal article, Original article

Publication year: 2010

Journal

Journal of the American Chemical Society American Chemical Society

Original Authors: Grimm B., Santos J., Illescas B.M., Munoz A., Guldi D.M., Martin N.

Publisher: American Chemical Society

Book Volume: 132

Pages Range: 17387-17389

Journal Issue: 49

DOI: 10.1021/ja108744a

Abstract

A new and readily available exTTF-bis(crown ether), 1, efficiently recognizes C as well as C by means of cooperative π-π and n-π interactions. The geometrical (concave-convex) and electronic (donor-acceptor) complementarity accounts on one hand for remarkable binding strengths, with association constants reaching 10 M in benzonitrile, and on the other hand for lifetimes of the photogenerated radical ion pair state on the order of 45 ps. © 2010 American Chemical Society.

Authors with CRIS profile

Bruno Grimm Graduiertenzentrum der FAU Dirk Michael Guldi Lehrstuhl für Physikalische Chemie I

Involved external institutions

Universidad Complutense de Madrid (UCM) ES Spain (ES)

How to cite

APA:

Grimm, B., Santos, J., Illescas, B.M., Munoz, A., Guldi, D.M., & Martin, N. (2010). A new exTTF-crown ether platform to associate fullerenes: Cooperative n-π and π-π Effects. Journal of the American Chemical Society, 132(49), 17387-17389. https://doi.org/10.1021/ja108744a

MLA:

Grimm, Bruno, et al. "A new exTTF-crown ether platform to associate fullerenes: Cooperative n-π and π-π Effects." Journal of the American Chemical Society 132.49 (2010): 17387-17389.

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