4-substituted tert-butyl phenylazocarboxylates-synthetic equivalents for the para-phenyl radical cation

Höfling S, Bartuschat A, Heinrich M (2010)

Publication Language: English

Publication Status: Published

Publication Type: Journal article, Original article

Publication year: 2010

Journal

Angewandte Chemie International Edition Wiley

Book Volume: 49

Pages Range: 9769-9772

Journal Issue: 50

DOI: 10.1002/anie.201004508

Abstract

First electrophile, then radical: 4-Substituted tert-butyl phenylazocarboxylates 1 are versatile synthetic equivalents of the para-phenyl radical cation 2. The tert-butyloxycarbonylazo group enables nucleophilic substitutions to proceed under mild conditions and can later be employed for the generation of aryl radicals. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Authors with CRIS profile

Amelie Bartuschat Professur für Pharmazeutische Chemie Markus Heinrich Professur für Pharmazeutische Chemie

How to cite

APA:

Höfling, S., Bartuschat, A., & Heinrich, M. (2010). 4-substituted tert-butyl phenylazocarboxylates-synthetic equivalents for the para-phenyl radical cation. Angewandte Chemie International Edition, 49(50), 9769-9772. https://doi.org/10.1002/anie.201004508

MLA:

Höfling, Sarah, Amelie Bartuschat, and Markus Heinrich. "4-substituted tert-butyl phenylazocarboxylates-synthetic equivalents for the para-phenyl radical cation." Angewandte Chemie International Edition 49.50 (2010): 9769-9772.

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