Eigler R, Heinemann FW, Hirsch A (2016)
Publication Status: Published
Publication Type: Journal article
Publication year: 2016
Book Volume: 22
Pages Range: 13575-81
Journal Issue: 38
Azafullerenes are as yet the only synthetically available heterofullerenes. Herein, we present plausible reaction pathways towards pentaaryl azafullerenes, focusing on the reactivity of hydro-azafullerene intermediates and their regiochemistry. The X-ray structure of a β'-hydro-tetraaryl adduct is presented for the first time. The reactivity of dihydro-azafullerene adducts is demonstrated here through H-abstraction in mass spectrometric experiments. Moreover, hydride abstraction and subsequent hydroxylation is possible, as well as deprotonation followed by alkylation.
APA:
Eigler, R., Heinemann, F.W., & Hirsch, A. (2016). Hydro-aza-(C59 N)fullerenes: Formation Mechanism and Hydrogen Substitution. Chemistry - A European Journal, 22(38), 13575-81. https://doi.org/10.1002/chem.201505115
MLA:
Eigler, Regina, Frank Wilhelm Heinemann, and Andreas Hirsch. "Hydro-aza-(C59 N)fullerenes: Formation Mechanism and Hydrogen Substitution." Chemistry - A European Journal 22.38 (2016): 13575-81.
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