Reactivity of U-E-U (E = S, Se) toward CO2, CS2, and COS: New mixed-carbonate complexes of the types U-CO2E-U (E = S, Se), U-CS2E-U (E = O, Se), and U-COSSe-U

Lam OP, Franke S, Heinemann FW, Meyer K (2012)

Publication Type: Journal article, Original article

Publication year: 2012

Journal

Journal of the American Chemical Society American Chemical Society

Original Authors: Lam O.P., Franke S.M., Heinemann F.W., Meyer K.

Publisher: American Chemical Society

Book Volume: 134

Pages Range: 16877-16881

Journal Issue: 40

DOI: 10.1021/ja307539w

Abstract

We recently reported the formation of a bridging carbonate complex [{((ArO)N)U}(μ-η: κ-CO)] via reductive cleavage of CO, yielding a μ-oxo bridged complex, followed by the insertion of another molecule of CO. In a similar strategy, we were able to isolate and characterize a series of mixed carbonate complexes U-COE-U, U-CSE-U, and even U-OC(S)Se-U, by reacting bridged chalcogenide complexes [{((ArO)N)U}(μ-E)] (E = S, Se) with CO, CS, and COS. These chalcogenido mixed-carbonate complexes represent the first of their kind. © 2012 American Chemical Society.

Authors with CRIS profile

Sebastian Franke Lehrstuhl für Anorganische und Allgemeine Chemie Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

How to cite

APA:

Lam, O.P., Franke, S., Heinemann, F.W., & Meyer, K. (2012). Reactivity of U-E-U (E = S, Se) toward CO2, CS2, and COS: New mixed-carbonate complexes of the types U-CO2E-U (E = S, Se), U-CS2E-U (E = O, Se), and U-COSSe-U. Journal of the American Chemical Society, 134(40), 16877-16881. https://doi.org/10.1021/ja307539w

MLA:

Lam, Oanh P., et al. "Reactivity of U-E-U (E = S, Se) toward CO2, CS2, and COS: New mixed-carbonate complexes of the types U-CO2E-U (E = S, Se), U-CS2E-U (E = O, Se), and U-COSSe-U." Journal of the American Chemical Society 134.40 (2012): 16877-16881.

BibTeX: Download