Pasgreta E, Puchta R, Zahl A, van Eldik R (2007)
Publication Type: Journal article, Original article
Publication year: 2007
Original Authors: Pasgreta E., Puchta R., Zahl A., Van Eldik R.
Publisher: Wiley-VCH Verlag
Book Volume: null
Pages Range: 1815-1822
Journal Issue: 13
Solutions of LiClO in solvent mixtures of acetonitrile and water, or acetonitrile and nitromethane, were studied by Li NMR spectroscopy. Measured chemical shifts indicate that the Li cation is coordinated by four acetonitrile molecules. In the binary water/acetonitrile mixture, water coordinates more strongly to Li than acetonitrile such that addition of writer immediately leads to the formation of [Li(H O)]. The solvent-exchange mechanism for [Li(L)] (L = CHCN and HCN) was studied by using DFT calculations (RB3LYP/6-311+G* *). This process was found to follow a limiting associative mechanism involving the formation of relatively stable five-coordinate intermediates. The suggested mechanisms are discussed with reference to available experimental and theoretical data. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
APA:
Pasgreta, E., Puchta, R., Zahl, A., & van Eldik, R. (2007). Ligand-exchange processes on solvated lithium cations: Acetonitrile and hydrogen cyanide. European Journal of Inorganic Chemistry, null(13), 1815-1822. https://doi.org/10.1002/ejic.200600930
MLA:
Pasgreta, Ewa, et al. "Ligand-exchange processes on solvated lithium cations: Acetonitrile and hydrogen cyanide." European Journal of Inorganic Chemistry null.13 (2007): 1815-1822.
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