la Pierre HS, Rosenzweig M, Kosog B, Hauser C, Heinemann FW, Liddle ST, Meyer K (2015)
Publication Status: Published
Publication Type: Journal article
Publication year: 2015
Publisher: Royal Society of Chemistry
Book Volume: 51
Pages Range: 16671-16674
Journal Issue: 93
DOI: 10.1039/c5cc07211e
The synthesis and characterization of uranium(VI) mono(imido) complexes, by the oxidation of corresponding uranium(V) species, are presented. These experimental results, paired with DFT analyses, allow for the comparison of the electronic structure of uranium(VI) mono(oxo) and mono(imido) ligands within a conserved ligand framework and demonstrate that the magnitude of the ground state stabilization derived from the inverse trans-influence (ITI) is governed by the relative charge localization on the multiply bonded atom or group.
APA:
la Pierre, H.S., Rosenzweig, M., Kosog, B., Hauser, C., Heinemann, F.W., Liddle, S.T., & Meyer, K. (2015). Charge control of the inverse trans-influence. Chemical Communications, 51(93), 16671-16674. https://doi.org/10.1039/c5cc07211e
MLA:
la Pierre, Henry Storms, et al. "Charge control of the inverse trans-influence." Chemical Communications 51.93 (2015): 16671-16674.
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