Puchta R, Galle M, van Eikema Hommes N, Pasgreta E, van Eldik R (2004)
Publication Status: Published
Publication Type: Journal article
Publication year: 2004
Publisher: American Chemical Society
Book Volume: 43
Pages Range: 8227-8229
Journal Issue: 26
DOI: 10.1021/ic0487979
The ligand exchange mechanism of solvated lithium cations has been studied using DFT calculations (RB3LYP/6-311+G**). The water exchange mechanism on [Li(H2O)(4)](+) was found to be limiting associative (A) involving a five-coordinate intermediate, whereas ammonia exchange on [Li(NH3)(4)](+) was found to follow an associative interchange (I-a) mechanism. The suggested mechanisms are discussed in reference to available experimental and theoretical data.
APA:
Puchta, R., Galle, M., van Eikema Hommes, N., Pasgreta, E., & van Eldik, R. (2004). Evidence for associative ligand exchange processes on solvated lithium cations. Inorganic Chemistry, 43(26), 8227-8229. https://doi.org/10.1021/ic0487979
MLA:
Puchta, Ralph, et al. "Evidence for associative ligand exchange processes on solvated lithium cations." Inorganic Chemistry 43.26 (2004): 8227-8229.
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