Hydrogen elimination in bulky calcium amidoborane complexes: Isolation of a calcium borylamide complex
Spielmann J, Harder S (2009)
Publication Type: Journal article, Original article
Publication year: 2009
Journal
Original Authors: Spielmann J., Harder S.
Publisher: American Chemical Society
Book Volume: 131
Pages Range: 5064-5065
Journal Issue: 14
DOI: 10.1021/ja901073c
Abstract
The decomposition route of N-substituted calcium amidoborane complexes depends on the steric bulk of the substituent. Relatively small substituents (R = H, Me, iPr) gave dehydrogenation to dimeric complexes with a bridging RN-BH-N(R)-BH ion, whereas the larger 2,6-diisopropylphenyl substituent resulted in formation of a complex with a borylamide anion: HB(R)N. This product is a promising species for (catalytic) regeneration with H, i.e., hydrogenation to the amidoborane anion HB(R)NH. © 2009 American Chemical Society.
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APA:
Spielmann, J., & Harder, S. (2009). Hydrogen elimination in bulky calcium amidoborane complexes: Isolation of a calcium borylamide complex. Journal of the American Chemical Society, 131(14), 5064-5065. https://doi.org/10.1021/ja901073c
MLA:
Spielmann, Jan, and Sjoerd Harder. "Hydrogen elimination in bulky calcium amidoborane complexes: Isolation of a calcium borylamide complex." Journal of the American Chemical Society 131.14 (2009): 5064-5065.
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