Bora-amidinate complexes of lanthanide(II) metals
Harder S, Naglav D (2010)
Publication Type: Journal article, Original article
Publication year: 2010
Journal
Original Authors: Harder S., Naglav D.
Publisher: Wiley-VCH Verlag
Pages Range: 2836-2840
Journal Issue: 18
Abstract
Reaction of (2-MeN-α-MeSi-benzyl) Ln·(thf) (Ln = Yb, Eu and Sm) with one equivalent of DIPP(H)N-BH-N(H)DIPP (NBN-H, DIPP = 2,6-iPr-phenyl) gave the first Ln boraamidinate complexes which crystallized in the presence of THF as NBN·Ln·(thf) . Although only the Sm and Eu complex crystallize isomorphic, all three show similar structures. The very small N-Ln-N' bite angles of 59.74(6)63.28(9)° leave a large part of the metal coordination sphere available for neutral thf ligands. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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APA:
Harder, S., & Naglav, D. (2010). Bora-amidinate complexes of lanthanide(II) metals. European Journal of Inorganic Chemistry, 18, 2836-2840. https://doi.org/10.1002/ejic.201000094
MLA:
Harder, Sjoerd, and Dominik Naglav. "Bora-amidinate complexes of lanthanide(II) metals." European Journal of Inorganic Chemistry 18 (2010): 2836-2840.
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