Prakash R, Götz A, Heinemann FW, Görling A, Sellmann D (2006)
Publication Type: Journal article, Original article
Publication year: 2006
Original Authors: Prakash R., Götz A.W., Heinemann F.W., Görling A., Sellmann D.
Publisher: American Chemical Society
Book Volume: 45
Pages Range: 4661-4667
Journal Issue: 12
DOI: 10.1021/ic060096j
Hydrazine nitrosation of [Ru(NO)(py S )] Br·THF (1) (py S = 2,6-bis(3-triphenylsilyl-2-sulfanylphenylthiomethyl)-pyridine ) in methanol/DMF led to the formation of mononuclear ammine complex [Ru(NH )(py S )] (2) and N O, whereas the reaction performed in THF/CH Cl /toluene afforded thioether-bridged dinuclear ammine complex [(NH )-Ru(μ-py S )Ru(py S )] (3). Compound 2 dimerizes in solution at room temperature to form 3 and is regenerated upon treatment of 3 with NH . A plausible mechanism for the hydrazine nitrosation of 1 has been proposed. The reaction of 1 with NH or N does not lead to a nucleophilic attack at the NO ligand but to a deprotonation that yields neutral nitrosyl complex [Ru(NO){py S (H )}] (4), which is supported by density functional theory calculations. © 2006 American Chemical Society.
APA:
Prakash, R., Götz, A., Heinemann, F.W., Görling, A., & Sellmann, D. (2006). Hydrazine nitrosation of a metal-bound nitric oxide: Structural evidence for the formation of an ammine complex. Inorganic Chemistry, 45(12), 4661-4667. https://doi.org/10.1021/ic060096j
MLA:
Prakash, R., et al. "Hydrazine nitrosation of a metal-bound nitric oxide: Structural evidence for the formation of an ammine complex." Inorganic Chemistry 45.12 (2006): 4661-4667.
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