Bachmann J (2005)
Publication Status: Published
Publication Type: Journal article, Review article
Publication year: 2005
Publisher: Elsevier
Book Volume: 249
Pages Range: 1316-1326
DOI: 10.1016/j.ccr.2005.03.034
Two-electron mixed valency is a useful design concept for hydrogen and oxygen photocatalysis. As single-electron mixed-valence compounds react in one-electron steps, two-electron mixed-valence compounds may react in two-electron steps at the constituent redox sites, whether they are metal- or ligand-based. With the redox centers working in concert upon photoexcitation, two- and four-electron transformations are promoted along excited-state pathways. Such a strategy is ideally suited to the activation of small molecules. We describe the photochemistry for hydrogen and oxygen activation using two-electron mixed-valence complexes of three different motifs: (a) M-n-Mn+2 bimetallic complexes, (b) tetrapyrrole macrocycles and (c) externally bridged di-iron(III) mu-oxo porphyrin dimers. (c) 2005 Elsevier B.V. All rights reserved.
APA:
Bachmann, J. (2005). Oxygen and hydrogen photocatalysis by two-electron mixed-valence coordination compounds. Coordination Chemistry Reviews, 249, 1316-1326. https://doi.org/10.1016/j.ccr.2005.03.034
MLA:
Bachmann, Julien. "Oxygen and hydrogen photocatalysis by two-electron mixed-valence coordination compounds." Coordination Chemistry Reviews 249 (2005): 1316-1326.
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