Multiple Bond Metathesis and N-AtomTransfer Chemistry Mediated by a Nucleophilic Uranium(V) Imido Complex

Castro-Rodriguez I, Nakai H, Meyer K (2006)

Publication Language: English

Publication Type: Journal article

Publication year: 2006

Journal

Angewandte Chemie International Edition Wiley

Book Volume: 45

Pages Range: 2389-2392

Journal Issue: 15

Abstract

Completing a circle of reactions: Reaction of a U^V–imido complex (2) with a π acid (e.g., CH₃NC) affords a U^IV–heterocumulene complex (3), which reacts with an alkyl halide to yield the free carbodiimide and corresponding U^IV–halide complex (4). Reduction of complex 4 recovers 1, thereby closing a cycle in which a nitrogen atom is transferred from a U^V–imido complex to a π acid by multiple-bond metathesis.

Authors with CRIS profile

Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Kyushu University / 九州大学

Japan (JP)

How to cite

APA:

Castro-Rodriguez, I., Nakai, H., & Meyer, K. (2006). Multiple Bond Metathesis and N-AtomTransfer Chemistry Mediated by a Nucleophilic Uranium(V) Imido Complex. Angewandte Chemie International Edition, 45(15), 2389-2392.

MLA:

Castro-Rodriguez, Ingrid, Hidetaka Nakai, and Karsten Meyer. "Multiple Bond Metathesis and N-AtomTransfer Chemistry Mediated by a Nucleophilic Uranium(V) Imido Complex." Angewandte Chemie International Edition 45.15 (2006): 2389-2392.

BibTeX: Download