Illner P, Puchta R, Heinemann FW, van Eldik R (2009)
Publication Status: Published
Publication Type: Journal article
Publication year: 2009
Pages Range: 2795-2801
Journal Issue: 15
DOI: 10.1039/b820940e
The coordinative behaviour of the bis(trifluoromethylsulfonyl)amide (NTf2-) anion was studied in terms of its interaction with the labile [Pd(terpyridine)Cl]Cl complex. Among various attempts to coordinate NTf2- to the Pd(II) centre, the complexes [Pd(terpyridine)NO3]NTf2 and [Pd(terpyridine)H2O](NTf2)2 were isolated and characterized. The crystallographic data for these complexes are presented and the possible coordination of the NTf2- anion to the metal centre is discussed in reference to DFT predictions.
APA:
Illner, P., Puchta, R., Heinemann, F.W., & van Eldik, R. (2009). Is bis(trifluoromethylsulfonyl)amide an innocent anion? X-ray structure data and DFT calculations. Dalton Transactions, 15, 2795-2801. https://doi.org/10.1039/b820940e
MLA:
Illner, Peter, et al. "Is bis(trifluoromethylsulfonyl)amide an innocent anion? X-ray structure data and DFT calculations." Dalton Transactions 15 (2009): 2795-2801.
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