Methandiide Complexes (R2CM2) of the Heavier Alkali Metals (M=Potassium, Rubidium, Cesium): Reaching the Limit?

Orzechowski L, Jansen G, Harder S (2009)

Publication Type: Journal article, Original article

Publication year: 2009

Journal

Angewandte Chemie International Edition Wiley

Original Authors: Orzechowski L., Jansen G., Harder S.

Publisher: Wiley-VCH Verlag

Book Volume: 48

Pages Range: 3825-3829

Journal Issue: 21

DOI: 10.1002/anie.200900830

Abstract

Size does matter: Whereas geminal bimetallic bis(amidophosphorano) methandiide complexes of the heavy alkali metals K and Rb are relatively stable, that of Cs, the largest and most electropositive of the alkali metals, decomposes to form a cyclic product, which cocrystallizes with benzylcesium. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

Authors with CRIS profile

Sjoerd Harder Lehrstuhl für Anorganische und Metallorganische Chemie

Involved external institutions

Universität Duisburg-Essen (UDE) DE Germany (DE)

How to cite

APA:

Orzechowski, L., Jansen, G., & Harder, S. (2009). Methandiide Complexes (R2CM2) of the Heavier Alkali Metals (M=Potassium, Rubidium, Cesium): Reaching the Limit? Angewandte Chemie International Edition, 48(21), 3825-3829. https://doi.org/10.1002/anie.200900830

MLA:

Orzechowski, Lars, Georg Jansen, and Sjoerd Harder. "Methandiide Complexes (R2CM2) of the Heavier Alkali Metals (M=Potassium, Rubidium, Cesium): Reaching the Limit?" Angewandte Chemie International Edition 48.21 (2009): 3825-3829.

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