Harder S (2011)
Publication Type: Journal article, Review article
Publication year: 2011
Original Authors: Harder S.
Publisher: Elsevier
Book Volume: 255
Pages Range: 1252-1267
DOI: 10.1016/j.ccr.2010.11.021
This review summarizes the rapid developments in the chemistry of phosphonium-stabilized group 1 and 2 methandiides, i.e. that of alkali and alkaline-earth metal bis(iminophosphorane)methandiide and bis(thiophosphorane)methandiide complexes. Apart from syntheses, structures and reactivities, also a critical discussion on bonding is given. The group 2 complexes of this type can truly be seen as polar metal carbene compounds with a formally polar double metal-carbon bond. © 2010 Elsevier B.V.
APA:
Harder, S. (2011). Geminal dianions stabilized by phosphonium substituents. Coordination Chemistry Reviews, 255, 1252-1267. https://doi.org/10.1016/j.ccr.2010.11.021
MLA:
Harder, Sjoerd. "Geminal dianions stabilized by phosphonium substituents." Coordination Chemistry Reviews 255 (2011): 1252-1267.
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