Reactions of dizincocene with sterically demanding bis(iminodi(phenyl) phosphorano)methanes

Schulz S, Gondzik S, Schuchmann D, Westphal U, Dobrzycki L, Boese R, Harder S (2010)

Publication Type: Journal article, Original article

Publication year: 2010

Journal

Chemical Communications Royal Society of Chemistry

Original Authors: Schulz S., Gondzik S., Schuchmann D., Westphal U., Dobrzycki L., Boese R., Harder S.

Publisher: Royal Society of Chemistry

Book Volume: 46

Pages Range: 7757-7759

Journal Issue: 41

DOI: 10.1039/c0cc02859b

Abstract

Reactions of Cp* Zn with sterically demanding bis(iminodi(phenyl)phosphorano)methanes LH (LH = CH (Ph PNR) (R = Ph L H, SiMe L H, 2,6-i-Pr C H (Dipp) L H) at ambient temperature occurred with elimination of Cp*H and subsequent formation of the homoleptic complex L Zn 1 and the heteroleptic complexes LZnZnCp* (L = L 2, L 3, L 4). 3 is the first structurally characterized heteroleptic organozinc complex with the zinc atoms in the formal oxidation state +1. © The Royal Society of Chemistry.

Authors with CRIS profile

Sjoerd Harder Lehrstuhl für Anorganische und Metallorganische Chemie

Involved external institutions

Universität Duisburg-Essen (UDE) DE Germany (DE)

How to cite

APA:

Schulz, S., Gondzik, S., Schuchmann, D., Westphal, U., Dobrzycki, L., Boese, R., & Harder, S. (2010). Reactions of dizincocene with sterically demanding bis(iminodi(phenyl) phosphorano)methanes. Chemical Communications, 46(41), 7757-7759. https://doi.org/10.1039/c0cc02859b

MLA:

Schulz, Stephan, et al. "Reactions of dizincocene with sterically demanding bis(iminodi(phenyl) phosphorano)methanes." Chemical Communications 46.41 (2010): 7757-7759.

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