Calcium amidoborane hydrogen storage materials: Crystal structures of decomposition products

Spielmann J, Jansen G, Bandmann H, Harder S (2008)

Publication Type: Journal article, Original article

Publication year: 2008

Journal

Angewandte Chemie International Edition Wiley

Original Authors: Spielmann J., Jansen G., Bandmann H., Harder S.

Publisher: Wiley-VCH Verlag

Book Volume: 47

Pages Range: 6290-6295

Journal Issue: 33

DOI: 10.1002/anie.200802037

Abstract

A model solution to hydrogen storage? The recently introduced hydrogen storage material [{Ca(NHBH)}] has been investigated on a molecular level. A hydrocarbon-soluble calcium amidoborane complex eliminates H spontaneously at the very low temperature of 20-40°C (see scheme). The decomposition product shows a dimeric species with a bridging [HN-BH-NH-BH] ion that is isolobal to the allylic dianion [HC-CH-CH-CH]. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Authors with CRIS profile

Sjoerd Harder Lehrstuhl für Anorganische und Metallorganische Chemie

Involved external institutions

Universität Duisburg-Essen (UDE) DE Germany (DE)

How to cite

APA:

Spielmann, J., Jansen, G., Bandmann, H., & Harder, S. (2008). Calcium amidoborane hydrogen storage materials: Crystal structures of decomposition products. Angewandte Chemie International Edition, 47(33), 6290-6295. https://doi.org/10.1002/anie.200802037

MLA:

Spielmann, Jan, et al. "Calcium amidoborane hydrogen storage materials: Crystal structures of decomposition products." Angewandte Chemie International Edition 47.33 (2008): 6290-6295.

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