Harder S, Ruspic C, Bhriain NN, Berkermann F, Schuermann M (2008)
Publication Type: Journal article, Original article
Publication year: 2008
Original Authors: Harder S., Ruspic C., Bhriain N.N., Berkermann F., Schürmannc M.
Publisher: Verlag der Zeitschrift Fuer Naturforschung
Book Volume: 63
Pages Range: 267-274
Journal Issue: 3
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-41049087106&origin=inward
A variety of benzyllanthanide complexes have been prepared by the metathesis reaction of benzylpotassium precursors with lanthanide halides. Syntheses and crystal structures for the following complexes are described: [2-MeN-α-MeSi-benzyl]Eu(II) ·(THF) (1-Eu), (2-MeN-benzyl)Ln(III) (2-Ln with Ln = Nd, Sm, Dy, Ho, Yb), (4-R-CHCH )Ln·(THF) (3-Y: Ln = Y, R = H; 3-La: Ln = La, R = tBu). Complexes of types 1 and 2 are thermally robust on account of a stabilization by a benzylic MeSi substituent and/or intramolecular coordination of the MeN substituent. Comparison of the crystal structures of these new series of lanthanide complexes shows several similarities and trends. In addition, comparisons with alkali metal and alkaline earth metal benzyl complexes are made. © 2008 Verlag der Zeitschrift für Naturforschung.
APA:
Harder, S., Ruspic, C., Bhriain, N.N., Berkermann, F., & Schuermann, M. (2008). Benzyl complexes of lanthanide(II) and lanthanide(III) metals: Trends and comparisons. Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, 63(3), 267-274.
MLA:
Harder, Sjoerd, et al. "Benzyl complexes of lanthanide(II) and lanthanide(III) metals: Trends and comparisons." Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences 63.3 (2008): 267-274.
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