Kindt S, Wicht K, Heinrich M (2015)
Publication Language: English
Publication Status: Published
Publication Type: Journal article, Original article
Publication year: 2015
Publisher: American Chemical Society
Book Volume: 17
Pages Range: 6122-6125
Journal Issue: 24
DOI: 10.1021/acs.orglett.5b03143
A new transition-metal-free version of the Meerwein arylation has been developed. The key feature of this carboamination-type reaction is the slow base-controlled generation of aryl radicals from aryldiazonium tetrafluoroborates, so that a sufficient quantity of diazonium ions remains to enable efficient trapping of the alkyl radical adduct resulting from aryl radical addition to the alkene. Under strongly basic conditions, diazoanhydrides are likely to take over the role of the nitrogen-centered radical scavengers.
APA:
Kindt, S., Wicht, K., & Heinrich, M. (2015). Base-Induced Radical Carboamination of Nonactivated Alkenes with Aryldiazonium Salts. Organic Letters, 17(24), 6122-6125. https://doi.org/10.1021/acs.orglett.5b03143
MLA:
Kindt, Stephanie, Karina Wicht, and Markus Heinrich. "Base-Induced Radical Carboamination of Nonactivated Alkenes with Aryldiazonium Salts." Organic Letters 17.24 (2015): 6122-6125.
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