Scheibel MG, Abbenseth J, Kinauer M, Heinemann FW, Wuertele C, De Bruin B, Schneider S (2015)
Publication Status: Published
Publication Type: Journal article
Publication year: 2015
Publisher: American Chemical Society
Book Volume: 54
Pages Range: 9290-9302
Journal Issue: 19
DOI: 10.1021/acs.inorgchem.5b00829
The redox series [Ir-n(NHx)(PNP)] (n = II-IV, x = 3-0; PNP = N(CHCHPtBu2)(2)) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir-III imido species [Ir(NH) (PNP)] is not stable but undergoes to the respective Ir-II amido and Ir-III nitrido species. N-H bond strengths are estimated upon reaction with hydrogen atom transfer reagents to rationalize this observation and are used to discuss the reactivity of these compounds toward E-H bond activation.
APA:
Scheibel, M.G., Abbenseth, J., Kinauer, M., Heinemann, F.W., Wuertele, C., De Bruin, B., & Schneider, S. (2015). Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, lmide, and Nitride Species. Inorganic Chemistry, 54(19), 9290-9302. https://doi.org/10.1021/acs.inorgchem.5b00829
MLA:
Scheibel, Markus G., et al. "Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, lmide, and Nitride Species." Inorganic Chemistry 54.19 (2015): 9290-9302.
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