Hümmer J, Heinemann FW, Meyer K (2017)
Publication Status: Published
Publication Type: Journal article
Publication year: 2017
Book Volume: 56
Pages Range: 3201-3206
Journal Issue: 6
DOI: 10.1021/acs.inorgchem.6b02123
We present the synthesis, characterization, and one-electron oxidation of two uranium(IV) complexes, coordinated to the cyclen-anchored tetrakis(aryloxide) ligands tetrakis-hydroxybenzyl-1,4,7,10 tetraazacyclododecane, (R,RArOH)4cyclen; R = tBu, Me. The new uranium(IV) and (V) complexes exhibit an eight-coordinate, tetragonal ligand environment, effecting exceptional stability of the coordinatively unsaturated uranium compounds. Cyclic voltammetry studies reveal redox events ranging from tri- to hexavalent species, covering an electrochemical window of ∼4 V.
APA:
Hümmer, J., Heinemann, F.W., & Meyer, K. (2017). Uranium Tetrakis-Aryloxide Derivatives Supported by Tetraazacyclododecane: Synthesis of Air-Stable, Coordinatively-Unsaturated U(IV) and U(V) Complexes. Inorganic Chemistry, 56(6), 3201-3206. https://doi.org/10.1021/acs.inorgchem.6b02123
MLA:
Hümmer, Julian, Frank Wilhelm Heinemann, and Karsten Meyer. "Uranium Tetrakis-Aryloxide Derivatives Supported by Tetraazacyclododecane: Synthesis of Air-Stable, Coordinatively-Unsaturated U(IV) and U(V) Complexes." Inorganic Chemistry 56.6 (2017): 3201-3206.
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