In-situ core-level photoelectron spectroscopy of adsorbates on surfaces involving a molecular beam - General setup and first experiments

Denecke R, Kinne M, Whelan C, Steinrück HP (2002)


Publication Type: Journal article

Publication year: 2002

Journal

Original Authors: Denecke R., Kinne M., Whelan C.M., Steinrück H.-P.

Publisher: World Scientific Publishing

Book Volume: 9

Pages Range: 797-801

Journal Issue: 2

DOI: 10.1142/S0218625X0200297X

Abstract

In this contribution we introduce a new apparatus combining high-resolution photoelectron spectroscopy and supersonic molecular beam techniques designed to follow simple surface reactions like adsorption, desorption or oxidation in situ in a time- and temperature-resolved manner. Using high brightness synchrotron radiation high resolution core-level spectra can be obtained in less than 3 s. The molecular beam allows for local pressures of up to 1 · 10 mbar and translational energies of the molecules of up to 2 eV in the case of CO. Preliminary examples of CO adsorption on Pt(111) are shown, where kinetic parameters can be derived from the coverage dependence of the different adsorption sites.

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How to cite

APA:

Denecke, R., Kinne, M., Whelan, C., & Steinrück, H.-P. (2002). In-situ core-level photoelectron spectroscopy of adsorbates on surfaces involving a molecular beam - General setup and first experiments. Surface Review and Letters, 9(2), 797-801. https://doi.org/10.1142/S0218625X0200297X

MLA:

Denecke, Reinhard, et al. "In-situ core-level photoelectron spectroscopy of adsorbates on surfaces involving a molecular beam - General setup and first experiments." Surface Review and Letters 9.2 (2002): 797-801.

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