Heinemann FW (2007)
Publication Status: Published
Publication Type: Journal article
Publication year: 2007
Publisher: BLACKWELL PUBLISHING
Book Volume: 63
Pages Range: M2769-U1290
DOI: 10.1107/S1600536807050970
The title solvated salt, [Ir(H)(2){P(C6H11)(3)}(2){OC(CH3)(2)}(2)]BF4 center dot-( CH3)(2)CO, was obtained by the protonation of [ Ir(H)(5)-{ P(C6H11)(3)}(2)] with HBF4 in acetone. The cation features OC-6- 13 stereochemistry, with Ir - P = 2.3159 ( 6) and 2.3267 ( 6) angstrom, and Ir - O = 2.238 ( 1) and 2.276 ( 1) angstrom. The BF4- anion shows threefold rotational disorder about a B - F bond, with site occupancies of 0.65, 0.25 and 0.10. While there are several intramolecular C-H center dot center dot center dot O and intermolecular C-H center dot center dot center dot F hydrogen-bonding interactions [ C center dot center dot center dot O = 3.207 ( 3)-3.358 ( 3)angstrom, and C center dot center dot center dot F = 3.434 ( 3) and 3.441 ( 3) angstrom], the O atom of the acetone solvent molecule does not act as a C - H acceptor.
APA:
Heinemann, F.W. (2007). (OC-6-13)-bis(acetone) dihydrido-bis(tricyclohexylphosphine)iridium(III) tetrafluoridoborate acetone solvate. Acta Crystallographica Section E: Structure Reports Online, 63, M2769-U1290. https://doi.org/10.1107/S1600536807050970
MLA:
Heinemann, Frank Wilhelm. "(OC-6-13)-bis(acetone) dihydrido-bis(tricyclohexylphosphine)iridium(III) tetrafluoridoborate acetone solvate." Acta Crystallographica Section E: Structure Reports Online 63 (2007): M2769-U1290.
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