Stabilization of a copper peroxido complex with a new binucleating ligand
Wuertele C, Heinemann FW, Schindler S (2010)
Publication Status: Published
Publication Type: Journal article
Publication year: 2010
Journal
Publisher: TAYLOR & FRANCIS LTD
Book Volume: 63
Pages Range: 2629-2641
Journal Issue: 14-16
DOI: 10.1080/00958972.2010.490876
Abstract
The ligand L(1) (N1,N3-di[2-di(2-pyridylmethyl)aminoethyl]N1,N3-dimethyl-1,3-propandiamine) bridges two tripodal units of the amine ligand Me(2)uns-penp (N1,N1-dimethyl-N2,N2-di(2-pyridylmethyl)-1,2-ethandiamine) with a propyl group. The ligand L(1), the dinuclear copper(I) complex [Cu(2)(L(1))](BPh(4))(2) and the dinuclear copper(II) complexes [Cu(2)Cl(2)(L(1))](ClO(4))(2), and Cu(2)Cl(2)(L(1))]Cl(2) have been synthesized and structurally characterized. The copper(I) complex reacts reversibly with dioxygen at low temperatures and forms a peroxido complex that is thermally more stable than the related peroxido complex formed from two mononuclear copper(I) complexes of the ligand Me(2)uns-penp.
Authors with CRIS profile
Involved external institutions
Germany (DE)How to cite
APA:
Wuertele, C., Heinemann, F.W., & Schindler, S. (2010). Stabilization of a copper peroxido complex with a new binucleating ligand. Journal of Coordination Chemistry, 63(14-16), 2629-2641. https://doi.org/10.1080/00958972.2010.490876
MLA:
Wuertele, Christian, Frank Wilhelm Heinemann, and Siegfried Schindler. "Stabilization of a copper peroxido complex with a new binucleating ligand." Journal of Coordination Chemistry 63.14-16 (2010): 2629-2641.
BibTeX: Download